The number of points of the poset minus the width of the poset.

The number of 1-protected nodes of a rooted tree. This is the number of nodes with minimal distance one to a leaf.

The number of distinct subtrees of an ordered tree. A subtree is specified by a node of the tree. Thus, the tree consisting of a single path has as many subtrees as nodes, whereas the tree of height two, having all leaves attached to the root, has only two distinct subtrees. Because we consider ordered trees, the tree $[[[[]], []], [[], [[]]]]$ on nine nodes has five distinct subtrees.

The hat guessing number of a graph. Suppose that each vertex of a graph corresponds to a player, wearing a hat whose color is arbitrarily chosen from a set of $q$ possible colors. Each player can see the hat colors of his neighbors, but not his own hat color. All of the players are asked to guess their own hat colors simultaneously, according to a predetermined guessing strategy and the hat colors they see, where no communication between them is allowed. The hat guessing number $HG(G)$ of a graph $G$ is the largest integer $q$ such that there exists a guessing strategy guaranteeing at least one correct guess for any hat assignment of $q$ possible colors. Because it suffices that a single player guesses correctly, the hat guessing number of a graph is the maximum of the hat guessing numbers of its connected components.

The largest eigenvalue of a graph if it is integral. If a graph is $d$-regular, then its largest eigenvalue equals $d$. One can show that the largest eigenvalue always lies between the average degree and the maximal degree. This statistic is undefined if the largest eigenvalue of the graph is not integral.

The largest multiplicity of a distance Laplacian eigenvalue in a connected graph. The distance Laplacian of a graph is the (symmetric) matrix with row and column sums $0$, which has the negative distances between two vertices as its off-diagonal entries. This statistic is the largest multiplicity of an eigenvalue. For example, the cycle on four vertices has distance Laplacian $$ \left(\begin{array}{rrrr} 4 & -1 & -2 & -1 \\ -1 & 4 & -1 & -2 \\ -2 & -1 & 4 & -1 \\ -1 & -2 & -1 & 4 \end{array}\right). $$ Its eigenvalues are $0,4,4,6$, so the statistic is $2$. The path on four vertices has eigenvalues $0, 4.7\dots, 6, 9.2\dots$ and therefore statistic $1$.

The multiplicity of the largest distance Laplacian eigenvalue in a connected graph. The distance Laplacian of a graph is the (symmetric) matrix with row and column sums $0$, which has the negative distances between two vertices as its off-diagonal entries. This statistic is the largest multiplicity of an eigenvalue. For example, the cycle on four vertices has distance Laplacian $$ \left(\begin{array}{rrrr} 4 & -1 & -2 & -1 \\ -1 & 4 & -1 & -2 \\ -2 & -1 & 4 & -1 \\ -1 & -2 & -1 & 4 \end{array}\right). $$ Its eigenvalues are $0,4,4,6$, so the statistic is $1$. The path on four vertices has eigenvalues $0, 4.7\dots, 6, 9.2\dots$ and therefore also statistic $1$. The graphs with statistic $n-1$, $n-2$ and $n-3$ have been characterised, see [1].

The number of indecomposable modules with projective dimension 2 for Nakayama algebras with global dimension at most 2.

The pebbling number of a connected graph.

The second largest eigenvalue of a graph if it is integral. This statistic is undefined if the second largest eigenvalue of the graph is not integral. Chapter 4 of [1] provides lots of context.